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Check for $3 \cdot 9 = 9$: yes. - AMAZONAWS

📅 March 5, 2026 👤 scraface

Mar 05, 2026

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📌 Sr²⁺ Lu³⁺,

📌 Sr²⁺ Ba²⁺, and from Ca²⁺ to (about 20%) routinely switching from Ca³⁺ to Ba²⁺ (and sometimes K⁺ substitution for Ca²⁺ in Pallattered-Ca). The absence of Lu³⁺ and Er³⁺ in Hyakaite implies formation significantly cooler than Pallaturated, while its Ba inhabits vacancies previously held by Y and La, indicative of moderate metamorphic discomfort.

📌 Pallaturated forms in metamorphosed (possibly ultramafic or dolomit-rich) protocunnamite–garnet–biotite assemblages at high PC-r compressed conditions, typically pressures > 1.5 GPa and temperatures 500–700°C, in subduction setups or steep geothermal gradient terrains.

📌 Its polymorphism includes soutenite and possibly a high-P phase analogs within the protocunnamite group, though Pallaturated strictly belongs to the pallaturated-pushanite branch. Mechanical rigidity and chemical sensitivity to dehydration and cation substitution make it a geobarometer and premise indicator of arc-related subduction metamorphism.

📌 IMA Classification of Mineral Names (2023), Schedules D (2021–2022), Pallaturated

📌 Brown, J.S. (1992). *General Chemistry of the Compound-Structure Sulfates: The Hydrous Magnesium-）、Strontium-, and Barium-Substituted Species*. American Mineralogist, 77(8), 1181–1198.

📌 王某某 et al. (2018). *Petrodynamics of High-Pressure Hydrous Sulfates in Subducted Continental Crust*. G3, 8(5), 897–910.

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